Energy/Energy efficiency Making the dream of climate-neutral air travel come true Producing carbon-neutral e-kerosene with the help of a CO 2 compressor The German non-profit organisation Atmosfair has opened the world's first plant for the industrial production of carbon-neutral e-kerosene. The aviation fuel is produced using renewable energies as well as CO 2 and H 2 . An important component of the pilot plant is Sauer Compressors' HAUG CO 2 compressor. The oilfree and hermetically gas-tight machine compresses atmospheric CO 2 to be used as raw material for the green kerosene. Carbon-neutral flying – the air transport industry's dream to make the business flourish again despite forthcoming restrictions regarding CO 2 emissions. According to the current state of technology, this only works on a large scale with e-kerosene, which is produced from renewable electricity. The so-called Power-to- Liquid fuels (PtL), a liquid combination of electrically generated H 2 and CO2, are to be added to conventional kerosene. That's how the German government envisions it according to their PtL roadmap. However, PtL is currently still considered too expensive for widespread use. The non-profit organisation Atmosfair is mainly known for offering offsets for greenhouse gases. Since 2021, the company has also been producing synthetic e-kerosene with a plant in Werlte, North Germany. The special feature of the pilot plant is that it produces the first carbon-neutral PtL kerosene ever! The founder and CEO explains: “As long as airplanes use kerosene, no matter if from fossil or renewable resources, they cause emissions. But for our production process we use CO 2 either from a biogas plant or directly extracted from the air. Thus, when the CO 2 eventually gets back Fig. 1: Full view of the PtL plant in Werlte, Germany. (Photo © : Atmosfair) into the atmosphere while the kerosene is burned, the carbon footprint is offset.” With a capacity of 350 tons of synthetic crude oil per year, the operation by far exceeds the bench scale. It is the first plant worldwide producing crude oil for e-kerosene approved by ASTM International for commercial aviation. The crude oil is added to fossil fuels in a refinery and distributed to several airlines with a balance sheet certificate (TÜV seal of approval). Electricity, hydrogen and CO 2 as raw materials The PtL plant uses the three main raw materials electricity, H 2 and CO 2 . The electricity comes exclusively from renewable resources without funding from the German Renewable Energy Sources Act (EEG). The hydrogen is produced from water by electrolysis using electrical energy. A proton exchange membrane (PEM) acts as the electrolyser and electrochemically splits water into hydrogen (H 2 ) and oxygen (O 2 ). One source of the CO 2 needed for the process is an on-site biogas plant. As the substrates used by the plant only contain carbon dioxide that they have previously extracted from the atmosphere during growth phase, the operation would already be climate-neutral only by re- Fig. 2: Inside the Direct Air Capture module: The compressor in front, the buffer storage for the CO 2 captured from the ambient air in the back. (Fig. 2-4 Photo © : Sauer Compressors) 26 PROCESS TECHNOLOGY & COMPONENTS 2022
Energy/Energy efficiency leasing the CO 2 . By reusing the waste CO 2 , the synthetic crude oil of the PtL plant is even achieving negative CO 2 emissions. The second source of CO 2 is the adsorption of CO 2 directly from the ambient air in the Direct Air Capture (DAC) process. An intake manifold sucks in air into a filter with a solvent that extracts the CO 2 and then binds it to a solid sorbent. Heat is then applied to the sorbent to release the CO 2 . Compressing the atmospheric CO 2 The carbon dioxide captured via DAC is stored in a balloon-like buffer. For further processing in the synthesis unit of the plant, the gas has to be compressed to a final pressure of 4.5 barg, which is technologically challenging. The CO 2 must not be contaminated, since the catalytic process requires pure gases without oil pollution that could permanently reduce or outweigh the process. Moreover, no CO 2 must get lost during the compression process. The solution is a gas compressor developed by the long-established Swiss company HAUG Sauer Kompressoren AG. The compressor has already proven to meet the highest gas purity and process quality requirements in several industries and research institutes. Modular oil-free and gas-tight compressor Fig. 3: The oil-free and hermetically gastight compressor compresses the CO 2 captured from the atmosphere. as well as intermittent operations, such as Atmosfair's application. Plus, it is hermetically gas-tight during operation and downtime, not allowing any CO 2 leakage. The reason is the non-contact and wear-free magnetic coupling, an in-house development, which can be used in the gas compressor of the HAUG.Neptune series for suction pressures of up to 14 barg. The modular concept of the compressor series allowed for an individual configuration to the requirements of the organisation. Pressure level and flow rate were therefore optimally adapted to the application via predefined cylinder modules. Synthetic crude oil for the refinery The last process step for the compressed CO 2 is the synthesis. In the synthesis unit, carbon dioxide and hydrogen are converted into a syngas, which is then used to produce synthetic crude oil, the primary product for the e-kerosene. This is done with the Fischer-Tropsch process. At temperatures of 150°C to 300°C, longchain hydrocarbons are formed in the presence of metal catalysts and eventually processed into climateneutral kerosene in a refinery. Sauer Compressors, Kiel, Germany This compressor is a completely oilfree and dry-running piston compressor that can be used for continuous Fig. 4: The compressor prior to its delivery in the factory hall of the compressor manufacturer. Certifi cate expired? Now switch to: KLINGERSIL ® C-4240 Germany The drinking water supply without compromises – Test confi rmation according to elastomer guideline valid until March 2026 PRIMUS AWARD SIEGER in der Kategorie DICHTUNGEN KLINGER GmbH, 65510 Idstein, Tel. +49 6126 40160, mail@klinger.de, www.klinger.de
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